IChO 2010 Logo 42nd International Chemistry Olympiad
Chemistry : the key to our future
⇒Japanese 
July 19-28 Home Participation Problem Sponsors Downloads Links
-
Regulations | Preparatory Problems | Errata | Problems (Solutions) | Results
-

Information for Mentors

[Corrections]
(Q1) Problem 12d: The sulfuric acid formed in step C is ignored in the official solution?
(A1) See the Revised Solution for Problem 12d. (31 March 2010)
 
(Q2) Solution 27c: The structure given is not a menthol (OH must be rearranged)?
(A2) It was wrong as you pointed out. Below is the correct structure. (12 April 2010)

 
(Q3) Solutions to Q17 (e) - (g) and Q18 (f) are missing?
(A3) For solutions to Q17 (e) - (g) and Q18 (d), (f), see the Addition to Solutions 17 and 18. See also the correction in Errata. (23 April 2010)
 
(Q4) Problem 16 (b) - the equations cannot be balanced without additional substances or unlikely products?
(A4) See the Revised Solution for Problems 16 and 20. (10 May 2010)
 
(Q5) Solution 20-a - the stoichiometric coefficient by the oxide is 2m/n ?
(A5) See the Revised Solution for Problems 16 and 20. (10 May 2010)
 
(Q6) Problem 21(a) - Could the organizers please explain why 28 is added to the denominator in the answer given? Also, the 109.8 term in the denominator is worked out only in part (b), so the order of parts seems reversed.
(A6) (a) Your suggestion is right. 28 should not be added in the equation.
(b) 109.8 mL was estimated in the previous question, 21(a).
See the revised solutions for Problem 21 (a). (1 July 2010)
 
[Responses to Comments]
(C1) Problem 13-a - the signs of the lattice energy in the task and in the solution are opposite?
(Re1) The example of the solution for the problem 13a is correct.
The definition of the lattice energy is "the energy required to separate completely the ions of a crystal to an infinite distance". Thus, the sign of the lattice energy is a plus. (31 March 2010)
 
(C2) Solution 20-a - the stoichiometric coefficient by the oxide is 2m/n?
(Re2) See (A5) in [Corrections] above. (Revised 10 May 2010)
 
(C3) Would you happen to know where we can buy the modified silica TLC plates that are used in problem 35?
(Re3) See the pdf file Suppl_info_problem_35.pdf. (8 Aptil 2010)
 
(C4) There is a mistake in problem 9 (e)?
The answer 9e is:
Calculate the energy width from the lowest occupied level to the highest occupied level.
I think that lowest occupied is wrong and the correct word is lowest unoccupied or LUMO.
This is also consistent with point (f) of the same problem.
(Re4) The gaps between discrete energy levels become narrower as the number of atoms increases in a one-dimensional quantum well model.
The descrete levels are treated as a broad band, when a sufficient number of atoms are involved.
The intention of problem 9(e) is to have the energy width of the occupied band, the energy difference between the lowest occupied level and the highest occupied level.

The description "the lowest occupied level" is good enough for Problem 9(e).

Could you please confirm the meaning from the solution? (8 Aptil 2010)
(C5) Problem 8 (f).
Question (f) should define atoms that looks like argon.
Personally I find Chlorine would be a better fit.
Don't you think there may be a mistake in your solution?
(Re5) Please see the "Correction to Preparatory Problem 8" in the Errata section. (30 April 2010)
 
(C6) We did not completely understand the details of the official solution of problem 21a.
A little more detail would be welcomed.
(Re6) Please see the Supplementary to Solution for Problem 21. (10 May 2010)
 
[Comments]
(1) See (C5) in [Responses to Comments] above.
 
(2) See (C4) in [Responses to Comments] above.
 
(3) See (Q4) in [Corrections] above.
 
(4) See (Q3) in [Corrections] above.
 
(5) See (Q3) in [Corrections] above.
 
(6) See (Q2) in [Corrections] above.
 
(7) See (C6) in [Responses to Comments] above.